This is how I write data items to a plist:
[myPlistFile setInteger: myInt forKey: @"someKey"];
Of course, you can change setInteger with setBool, etc for different types.
Hope this helps!
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Edit:
If your .plist was a member of an important class or similar...
Header of myClass:
NSUserDefaults* myPreferences;
@property (nonatomic, retain) NSUserDefaults* myPreferences;
.m of myClass:
self.myPreferences = [NSUserDefaults standardUserDefaults]; // load our preferences
[[NSUserDefaults standardUserDefaults] registerDefaults: [NSDictionary dictionaryWithContentsOfFile: [[NSBundle mainBundle]pathForResource: @"nameOfFile" ofType: @"plist"]]]; // now load the custom .plist file
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