Based off of what I have in my bootstrap.css file, the default is a max-width property.
I use this
.popover {
position: absolute;
top: 0;
left: 0;
z-index: 1010;
display: none;
max-width: 600px;
padding: 1px;
text-align: left;
white-space: normal;
background-color: #ffffff;
border: 1px solid #ccc;
border: 1px solid rgba(0, 0, 0, 0.2);
-webkit-border-radius: 6px;
-moz-border-radius: 6px;
border-radius: 6px;
-webkit-box-shadow: 0 5px 10px rgba(0, 0, 0, 0.2);
-moz-box-shadow: 0 5px 10px rgba(0, 0, 0, 0.2);
box-shadow: 0 5px 10px rgba(0, 0, 0, 0.2);
-webkit-background-clip: padding-box;
-moz-background-clip: padding;
background-clip: padding-box;
}
and it works exactly how you intended it to.
My bootstrap.css files does not contain a popover-inner a css selector at all though
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